I have the Trilogy box set, myself. As far as I know, the discs in the set that I have are identical to the discs in the 2-disc Spiderman 3 release by itself, though there are some minor packaging variation (the color of the 'spine' on the box set version of the movie is blue, while the single release is red).
As for the single disc version that came with PS3, I do not have it, but I am fairly certain that the disc, itself, is just the same as disc 1 in the 2-disc sets. I don't see why it wouldn't work in other BD players, and I've never heard anyone else say that they've had a problem using it in other players and I don't see why it wouldn't, but I guess I could be wrong. They just didn't include the second disc with the extras in it as far as I can tell.
I don't see why they would go out of their way to make the disc incompatible with other Blu-Ray players. That just doesn't make any sense to me.
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