To me it's Spider-Man 3 probably
Didn't think about the question for long, but Spider-Man 3 came to my mind. Yes, it's goofy and probably has too many villains, but in times of overblown MCU it feels pretty grounded to me. I always feel like this could've been the best Spider-Man if Sony hadn't tampered with it. Watching it again, I have to admit I enjoy it - maybe because of the meme factor as well. But still, I kinda like it
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