Just the generally obvious things:
- Make sure the controller is properly charged (you might even want to try using the controller with it actually connected via the usb cable).
- Make sure the controller is assigned as Controller 1 (I don't think you'd be able to play at all if it wasn't, but who knows).
- Shut down and restart the PS3.
- Make sure you have the latest firmware installed.
- Try the controller with other games that use the Six Axis motion controls (download the Super Rub a Dub demo and see that game works).
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