If they like classics, use 2001 or Blade Runner to show how good an old movie can look on blu-ray.
Others...
I, Robot
Cars
POTC (any of them)
I am Legend
Casino Royale
Planet Earth Series
Galapagos
Sunshine
Live Free or Die Hard
Kingdom of Heaven
Spiderman 3
Fantastic 4: Rise of the Silver Surfer
Mr. & Mrs. Smith
Deja Vu (great scene at the beginning -- Ferry blowing up)
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